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<article language="en">
	<journal>
		<journal_title>Hydrology and Earth System Sciences</journal_title>
		<journal_url>www.hydrol-earth-syst-sci.net</journal_url>
		<issn>1027-5606</issn>
		<eissn>1607-7938</eissn>
		<volume_number>11</volume_number>
		<issue_number>5</issue_number>
		<publication_year>2007</publication_year>
	</journal>
	<doi>10.5194/hess-11-1621-2007</doi>
	<article_url>http://www.hydrol-earth-syst-sci.net/11/1621/2007/</article_url>
	<abstract_html>http://www.hydrol-earth-syst-sci.net/11/1621/2007/hess-11-1621-2007.html</abstract_html>
	<fulltext_pdf>http://www.hydrol-earth-syst-sci.net/11/1621/2007/hess-11-1621-2007.pdf</fulltext_pdf>
	<start_page>1621</start_page>
	<end_page>1631</end_page>
	<publication_date>2007-09-28</publication_date>
	<article_title content_type="html">Tracing and quantifying groundwater inflow into lakes using a simple method for radon-222 analysis</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>T. Kluge</name>
			<email>tobias.kluge@iup.uni-heidelberg.de</email>
		</author>
		<author numeration="2" affiliations="1">
			<name>J. Ilmberger</name>
		</author>
		<author numeration="3" affiliations="1">
			<name>C. von Rohden</name>
		</author>
		<author numeration="4" affiliations="1">
			<name>W. Aeschbach-Hertig</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Institute for Environmental Physics, University of Heidelberg, Im Neuenheimer Feld 229, 69120 Heidelberg, Germany</affiliation>
	</affiliations>
	<abstract content_type="html">Due to its high activities in groundwater, the radionuclide &lt;sup&gt;222&lt;/sup&gt;Rn is a
sensitive natural tracer to detect and quantify groundwater inflow into
lakes, provided the comparatively low activities in the lakes can be
measured accurately. Here we present a simple method for radon measurements
in the low-level range down to 3 Bq m&lt;sup&gt;&amp;minus;3&lt;/sup&gt;, appropriate for
groundwater-influenced lakes, together with a concept to derive inflow rates
from the radon budget in lakes. The analytical method is based on a
commercially available radon detector and combines the advantages of
established procedures with regard to efficient sampling and sensitive
analysis. Large volume (12 l) water samples are taken in the field and
analyzed in the laboratory by equilibration with a closed air loop and alpha
spectrometry of radon in the gas phase. After successful laboratory tests,
the method has been applied to a small dredging lake without surface in- or
outflow in order to estimate the groundwater contribution to the
hydrological budget. The inflow rate calculated from a &lt;sup&gt;222&lt;/sup&gt;Rn balance
for the lake is around 530 m³ per day, which is comparable to the
results of previous studies. In addition to the inflow rate, the vertical
and horizontal radon distribution in the lake provides information on the
spatial distribution of groundwater inflow to the lake. The simple
measurement and sampling technique encourages further use of radon to
examine groundwater-lake water interaction.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Burnett, W. C., Kim, G., and Lane-Smith, D.: A continuous monitor for assessment of $^222$Rn in the coastal ocean, J. Radioanal. Nucl. Chem., 249, 167&amp;ndash;172, 2001. </reference>
		<reference numeration="2" content_type="text"> Cable, J. E., Bugna, G. C., Burnett, W. C., and Chanton, J. P.: Application of $^222$Rn and CH&lt;sub&gt;4&lt;/sub&gt; for assessment of groundwater discharge to the coastal ocean, Limnol. Oceanogr., 41, 1347&amp;ndash;1353, 1996. </reference>
		<reference numeration="3" content_type="text"> Colman, J. A. and Armstrong, D. E.: Vertical eddy diffusivity determined with $^222$Rn in the benthic boundary layer of ice-covered lakes, Limnol. Oceanogr., 32, 577&amp;ndash;590, 1987. </reference>
		<reference numeration="4" content_type="text"> Corbett, R., Burnett, W. C., Cable, P. H., and Clark, S. B.: Radon tracing of groundwater input into Par Pond, Savannah River Site, J. Hydrol., 203, 209&amp;ndash;227, 1997. </reference>
		<reference numeration="5" content_type="text"> Corbett, R., Dillon, K., Burnett, W. C., Chanton, J., and Rutkowki, C.: Patterns of groundwater discharge into Florida Bay, Limnol. Oceanogr., 44, 1045&amp;ndash;1055, 1999. </reference>
		<reference numeration="6" content_type="text"> Corbett, R., Dillon, K., Burnett, W. C., and Chanton, J.: Estimating the groundwater contribution into Florida Bay via natural tracers, Rn-222 and CH-4, Limnol. Oceanogr., 45, 1546&amp;ndash;1557, 2000. </reference>
		<reference numeration="7" content_type="text"> Crusius, J., Koopmans, D., Bratton, J. F., Charette, M. A., Kroeger, K. D., Henderson, P., Ryckman, L., Halloran, K., and Colman, J. A.: Submarine groundwater discharge to a small estuary estimated from radon and salinity measurements and a box model, Biogeosciences, 2, 141&amp;ndash;157, 2005. </reference>
		<reference numeration="8" content_type="text"> Dulaiova, H., Peterson, R., Burnett, W. C., and Lane-Smith, D.: A multi-detector continuous monitor for assessment of $^222$Rn in the coastal ocean, J. Radioanal. Nucl. Chem., 263, 361&amp;ndash;365, 2005. </reference>
		<reference numeration="9" content_type="text"> Durridge Co.: RAD7 radon detector &amp;ndash; Owner&apos;s manual, available at http://www.durridge.com/Manuals.htm, 2000. </reference>
		<reference numeration="10" content_type="text"> Durridge Co.: RAD7 RAD-H&lt;sub&gt;2&lt;/sub&gt;0 &amp;ndash; Radon in water accessory &amp;ndash; Owner&apos;s manual, available at http://www.durridge.com/Manuals.htm, 2001a. </reference>
		<reference numeration="11" content_type="text"> Durridge Co.: RAD AQUA &amp;ndash; Continuous radon-in-water monitoring system, available at http://www.durridge.com/Manuals.htm, 2001b. </reference>
		<reference numeration="12" content_type="text"> Hoehn, E. and von Gunten, H.: Radon in groundwater: a tool to assess infiltration from surface waters to aquifers, Water Resour. Res., 25, 1795&amp;ndash;1803, 1989. </reference>
		<reference numeration="13" content_type="text"> HGK, Arbeitsgruppe Hydrogeologische Kartierung und Grundwasserbewirtschaftung Rhein-Neckar-Raum: Hydrogeologische Kartierung und Grundwasserbewirtschaftung Rhein-Neckar-Raum, Analyse des Ist-Zustandes, Technical report, Ministerium für Ernährung, Landwirtschaft, Umwelt und Forsten Baden-Württemberg, Hessischer Minister für Landesentwicklung, Umwelt, Landwirtschaft und Forsten, Ministerium für Landwirtschaft, Weinbau und Forsten Rheinland-Pfalz, 1999. </reference>
		<reference numeration="14" content_type="text"> Imboden, D. and Emerson, S.: Natural radon and phosphorus as limnologic tracers: Horizontal and vertical eddy diffusion in Greifensee, Limnol. Oceanogr., 29, 831&amp;ndash;844, 1984. </reference>
		<reference numeration="15" content_type="text"> Kawabata, H., Narita, H., Harada, K., Tsunogai, S., and Kusakabe, M.: Air-sea gas transfer velocity in stormy winter estimated from radon deficiency, J. Oceanogr., 59, 651&amp;ndash;661, 2003. </reference>
		<reference numeration="16" content_type="text"> Kluge, T.: Radon als Tracer in aquatischen Systemen, Diploma thesis, Univ. Heidelberg, 2005. </reference>
		<reference numeration="17" content_type="text"> Krabbenhoft, D. P., Bowser, C. J., Anderson, M. P., and Valley, J. W.: Estimating groundwater exchange with lakes 1. The stable isotope mass balance method, Water Resour. Res., 26, 2445&amp;ndash;2453, 1990. </reference>
		<reference numeration="18" content_type="text"> Lambert, M. J. and Burnett, W. C.: Submarine groundwater discharge estimates at a Florida coastal site based on continuous radon measurements, Biogeochem., 66, 55&amp;ndash;73, 2003. </reference>
		<reference numeration="19" content_type="text"> Laukenmann, S.: Transport und Austausch redoxsensitiver Elemente zwischen Freiwasser und Sediment in einem eutrophen Hartwassersee (Willersinnweiher/Ludwigshafen), unter besonderer Berücksichtigung des geochemischen Verhaltens von Uran, Ph.D. thesis., Univ. Heidelberg, 2002. </reference>
		<reference numeration="20" content_type="text"> Lee, D. R.: A device for measuring seepage flux in lakes and estuaries, Limnol. Oceanogr., 22, 140&amp;ndash;147, 1977. </reference>
		<reference numeration="21" content_type="text"> Levin, I., Born, M., Cuntz, M., Langendörfer, U., Mantsch, S., Naegler, T., Schmidt, M., Verlagin, A., Verclas S., and Wagenbach, D.: Observations of atmospheric variability and soil exhalation rate of radon-222 at a Russian forest site, Tellus, 54B, 462&amp;ndash;475, 2002. </reference>
		<reference numeration="22" content_type="text"> Mathieu, G. G., Biscaye, P. E., and Lupton, R. A.: System for measurement of Rn-222 at low levels in natural waters, Health Phys., 55, 982&amp;ndash;992, 1988. </reference>
		<reference numeration="23" content_type="text"> Peeters, F., Wüest, A., Piepke, G., and Imboden, D.: Horizontal mixing in lakes, J. Geophys. Res., 101, 18 361&amp;ndash;18 375, 1996. </reference>
		<reference numeration="24" content_type="text"> Roether, W. and Kromer, B.: Field determination of air-sea gas exchange by continuous measurement of radon-222, Pure Appl. Geophys., 116, 476&amp;ndash;485, 1978. </reference>
		<reference numeration="25" content_type="text"> Sandler, B.: Die Wirkung von Sanierungs- und Restaurierungsmaßnahmen auf die Nährstoffströme und die biotische Dynamik eines anthropogenen Gewässers am Beispiel des Willersinnweihers/Ludwigshafen, Ph.D. thesis, Univ. Heidelberg, 2000. </reference>
		<reference numeration="26" content_type="text"> Schmid, J.: Calcitfällung und Phosphor-Kopräzipitation im Phosphorhaushalt eines eutrophen Hartwassersees mit anoxischem Hypolimnion (Willersinnweiher, Ludwigshafen am Rhein), Ph.D. thesis., Univ. Heidelberg, 2002. </reference>
		<reference numeration="27" content_type="text"> Schubert, M., Knoeller, K., Treutler, H.-C., Weiss, H., Dehnert, J.: $^222$Rn as a tracer for the estimation of infiltration of surface waters into aquifers, in: Radionuclides in the environment, edited by: Povinec, P. P. and Sanchez-Cabeza, J. A., Radioactivity in the environment, Vol. 8, Elsevier, Amsterdam, 326&amp;ndash;334, 2006. </reference>
		<reference numeration="28" content_type="text"> Schwartz, M. C.: Significant groundwater input to a coastal plain estuary: assessment from excess radon, Estuar. Coast. Shelf S., 56, 31&amp;ndash;42, 2003. </reference>
		<reference numeration="29" content_type="text"> Trettin, R., Gläßer, W., Lerche, I., Seelig, U., and Treutler, H.-C.: Flooding of lignite mines: isotope variations and processes in a system influenced by saline groundwater, Isot. Environ. Health S., 42, 159&amp;ndash;179, 2006. </reference>
		<reference numeration="30" content_type="text"> Tuccimei, P., Salvati, R., Capelli, G., Delitala, M. C., and Primavera, P.: Groundwater fluxes into a submerged sinkhole area, Central Italy, using radon and water chemistry, Appl. Geochem., 20, 1831&amp;ndash;1847, 2005. </reference>
		<reference numeration="31" content_type="text"> Upstill-Goddard, R. C., Watson, A. J., Liss, P. S., and Liddicoat, M.: Gas transfer velocities in lakes measured with SF$_6$, Tellus, 42B, 364&amp;ndash;377, 1990. </reference>
		<reference numeration="32" content_type="text"> von Rohden, C. and Ilmberger, J.: Tracer experiment with sulfur hexafluoride to quantify the vertical transport in a meromictic pit lake, Aquat. Sci., 63, 417&amp;ndash;431, 2001. </reference>
		<reference numeration="33" content_type="text"> von Rohden, C., Wunderle, K., and Ilmberger, J.: Parameterisation of the vertical transport in a small thermally stratified lake, Aquat. Sci., 69, 129&amp;ndash;137, doi:10.1007/s00027-006-0827-4, 2007. </reference>
		<reference numeration="34" content_type="text"> Wanninkhof, R.: Relationship Between Wind Speed and Gas Exchange Over the Ocean, J. Geophys. Res., 97, 7373&amp;ndash;7382, 1992. </reference>
		<reference numeration="35" content_type="text"> Weigel, F.: Radon, Chemiker-Zeitung, 102, 287&amp;ndash;298, 1978. </reference>
		<reference numeration="36" content_type="text"> Wollschläger, U.: Kopplung zwischen Oberflächenwasser und Grundwasser: Modellierung und Analyse von Umwelttracern, Ph.D. thesis., Univ. Heidelberg, 2003. </reference>
		<reference numeration="37" content_type="text"> Wollschläger, U., Ilmberger, J., Isenbeck-Schröter, M., Kreuzer, A., von Rhoden, C., Roth, K. and Schäfer, W.: Coupling of groundwater and surface water at Lake Willersinnweiher: Groundwater modeling and tracer studies, Aquat. Sci., 69, 138&amp;ndash;152, doi:10.1007/s00027-006-0825-6, 2007. </reference>
		<reference numeration="38" content_type="text"> Yehdegho, B., Rozanski, K., Zojer, H., and Stichler, W.: Interaction of dredging lakes with the adjacent groundwater field: an isotope study, J. Hydrol., 192, 247&amp;ndash;270, 1997. </reference>
	</references>
</article>

