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<article language="en">
	<journal>
		<journal_title>Hydrology and Earth System Sciences</journal_title>
		<journal_url>www.hydrol-earth-syst-sci.net</journal_url>
		<issn>1027-5606</issn>
		<eissn>1607-7938</eissn>
		<volume_number>11</volume_number>
		<issue_number>6</issue_number>
		<publication_year>2007</publication_year>
	</journal>
	<doi>10.5194/hess-11-1771-2007</doi>
	<article_url>http://www.hydrol-earth-syst-sci.net/11/1771/2007/</article_url>
	<abstract_html>http://www.hydrol-earth-syst-sci.net/11/1771/2007/hess-11-1771-2007.html</abstract_html>
	<fulltext_pdf>http://www.hydrol-earth-syst-sci.net/11/1771/2007/hess-11-1771-2007.pdf</fulltext_pdf>
	<start_page>1771</start_page>
	<end_page>1781</end_page>
	<publication_date>2007-11-16</publication_date>
	<article_title content_type="html">Metal contamination budget at the river basin scale: an original Flux-Flow Analysis (F2A) for the Seine River</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>L. Lestel</name>
		</author>
		<author numeration="2" affiliations="2">
			<name>M. Meybeck</name>
		</author>
		<author numeration="3" affiliations="3">
			<name>D. R. Thévenot</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Centre d&apos;Histoire des Techniques et de l&apos;Environnement, CNAM, case I-161, 5 rue du Vertbois, 75003 Paris, France</affiliation>
		<affiliation numeration="2" content_type="html">UMR Sisyphe 7619, Université P. et M. Curie, boite 105, 4 place Jussieu, 75006 Paris, France</affiliation>
		<affiliation numeration="3" content_type="html">Centre d&apos;Enseignement et de Recherche sur l&apos;Eau, la Ville et l&apos;Environnement (Cereve), UMR-MA 102, Université Paris 12 Val de Marne, Faculté de Sciences et Technologie, 61 Avenue du Général de Gaulle, 94010 Créteil Cedex, France</affiliation>
	</affiliations>
	<abstract content_type="html">Material flow analysis and environmental contamination analysis are merged
into a Flux-Flow analysis (F2A) as illustrated for the metal circulation in
the Seine River catchment. F2A combines about 30 metal flows in the
anthroposphere (14 million people) and/or metal fluxes in the environment
(atmosphere, soils, and aquatic system) originating from two dozens of
sources. The nature and quality of data is very heterogeneous going from
downscaled national economic statistics to upscaled daily environmental
surveys.
&lt;br&gt;&lt;br&gt;
A triple integration is performed: space integration over the catchment
(65 000 km&lt;sup&gt;2&lt;/sup&gt;), time integration for the 1950&amp;ndash;2000 trend analysed at
5 year resolution, and a conceptual integration resulting in two F2A
indicators.
&lt;br&gt;&lt;br&gt;
Despite the various data sources an average metal circulation is established
for the 1994&amp;ndash;2003 period and illustrated for zinc: (i) metal circulation in
the anthroposphere is now two orders of magnitude higher than river outputs,
(ii) long term metal storage, and their potential leaks, in soils,
wastedumps and structures is also orders of magnitude higher than present
river fluxes. Trend analysis is made through two F2A indicators, the per
capita excess load at the river outlet and the leakage ratio (excess
fluxes/metal demand). From 1950 to 2000, they both show a ten fold
improvement of metal recycling while the metal demand has increased by 2.5
to 5 for Cd, Cu, Cr, Pb and Zn, and the population by 50%.</abstract>
	<references>
		<reference numeration="1" content_type="text"> AESN: Priority pollutant released by industries upstream the Seine River mouth: first results of the 2005&amp;ndash;2006 campaign, AESN, Nanterre, 2006. </reference>
		<reference numeration="2" content_type="text"> Azimi, S., Ludwig, A., Thévenot, D. R., and Colin, J. L.: Trace metal determination in total atmospheric deposition in rural and urban areas, Sci. Total Environ., 308, 247&amp;ndash;256, 2003. </reference>
		<reference numeration="3" content_type="text"> Azimi, S., Rocher, V., Garnaud, S., Varrault, G., and Thévenot, D.: Decrease of atmospheric deposition of heavy metals in an urban area from 1994 to 2002 (Paris, France), Chemosphere, 61, 645&amp;ndash;651, 2005. </reference>
		<reference numeration="4" content_type="text"> Baccini, P. and Brunner, P. H.: Metabolism of the Anthroposphere, Springer-Verlag, Berlin, 1991. </reference>
		<reference numeration="5" content_type="text"> Barles, S.: La ville délétère, Champ Vallon, Seyssel, 1999. </reference>
		<reference numeration="6" content_type="text"> Bergbäck, B., Johansson, K., and Molhander, U.: Urban metal flows &amp;ndash; a case study of Stockholm, Review and Conclusions, Water Air Soil Pollut. Focus, 1(3&amp;ndash;4), 3&amp;ndash;24, 2001. </reference>
		<reference numeration="7" content_type="text"> Billen, G., Toussaint, F., Peters, P., Sapir, M., Steenhout, A., and Vanderborght, J. P: L&apos;écosystème Belgique, Essai d&apos;écologie industrielle, CRISP, Bruxelles, 163 pp., 1983. </reference>
		<reference numeration="8" content_type="text"> Billen, G., Garnier, J., Némery, J., Sebilo, M., Sferratore, A., Barles, S., Benoit, P., and Benoît, M.: A long-term view of nutrient transfers through the Seine river continuum, Sci. Total Environ., 375, 80&amp;ndash;97, 2007. </reference>
		<reference numeration="9" content_type="text"> Brunner, P. H. and Rechberger, H.: Practical Handbook of Material Flow Analysis, Lewis Publishers, New York, 2004. </reference>
		<reference numeration="10" content_type="text"> Cave, R. R., Ledoux, L., Turner, K., Jickells, T., Andrews, J. E., and Davies, H.: The Humber catchment and its coastal area: from UK to European perspectives, Sci. Total Environ., 314&amp;ndash;316, 31&amp;ndash;52, 2003. </reference>
		<reference numeration="11" content_type="text"> Ciais, P., Borges, A. V., Abril, G., Meybeck, M., Folberth, G., Hauglustaine, D., and Janssens, I. A.: The impact of lateral carbon fluxes on the European carbon balance, Biogeosciences Discuss., 3, 1529&amp;ndash;1559, 2006. </reference>
		<reference numeration="12" content_type="text"> CITEPA: Calcul des émissions dans l&apos;air, Principes méthologiques généraux, www.citepa.org, CITEPA, Paris, 2004. </reference>
		<reference numeration="13" content_type="text"> EEA: Corine Land Cover, http://dataservice.eea.eu.int/dataservice, European Environment Agency, Copenhagen, 2000. </reference>
		<reference numeration="14" content_type="text"> EauFrance: Rejets industriels, 1998 to 2002 data, www.eaufrance.fr, Ministère de l&apos;Ecologie et du Développement Durable, Paris, 2004. </reference>
		<reference numeration="15" content_type="text"> FEDEM (Fédération des métaux non ferreux): L&apos;industrie des minerais, minéraux industriels et métaux non ferreux, Chiffres clés 2002, FEDEM, Paris, 2003. </reference>
		<reference numeration="16" content_type="text"> Garnaud, S., Mouchel, J. M., Chebbo, G., and Thévenot, D.: Heavy metal concentrations in dry and wet atmospheric deposits in Paris district: comparison with urban runoff, Sci. Total Environ., 235, 235&amp;ndash;245, 1999. </reference>
		<reference numeration="17" content_type="text"> Gombert, S., Rausch de Traubenberg, C., Losno, R., Leblond, S., Colin, J. L., and Cossa, D.: Biomonitoring of element deposition using mosses, in the 2000 French survey: identifying sources and spatial trends, J. Atmos. Chem., 49, 479&amp;ndash;502, 2004. </reference>
		<reference numeration="18" content_type="text"> Graedel, T. E. and Allendy, B. R.: Industrial Ecology, 2nd edition, Prentice Hall, Pearson Education Inc., Upper Saddle River, New Jersey, 2003. </reference>
		<reference numeration="19" content_type="text"> Gromaire, M. C., Chebbo, G., and Constant, A.: Impact of zinc roofing on urban runoff pollutant loads: the case of Paris, Water Sci. Technol., 45(7), 113&amp;ndash;122, 2002. </reference>
		<reference numeration="20" content_type="text"> Grosbois, C., Meybeck, M., Horowitz, A., and Ficht, A.: The spatial and temporal trends of Cd, Cu, Hg, Pb and Zn in Seine River floodplain deposits (1994&amp;ndash;2000), Sci. Total Environ., 356, 22&amp;ndash;37, 2006. </reference>
		<reference numeration="21" content_type="text"> Grousset, F. E., Jouanneau, J. M., Castaing, P., Lavaux, G., and Latouche, C.: A 70 year record of contamination from industrial activity along the Garonne River and its tributaries (SW France), Estuarine, Coastal and Shelf Sci., 48, 401&amp;ndash;414, 1999. </reference>
		<reference numeration="22" content_type="text"> Harland, J., Taylor, D., and Wither, A.: The distribution of mercury and other trace metals in the sediments of the Mersey estuary over 25 years, 1974&amp;ndash;1998, Sci. Total Environ., 253, 45&amp;ndash;62, 2000. </reference>
		<reference numeration="23" content_type="text"> Horowitz, A. J.: A primer on sediment-trace element chemistry, 2nd ed., Lewis publishers Inc, Chelsea, MI, 1991. </reference>
		<reference numeration="24" content_type="text"> Horowitz, A. J., Meybeck, M., Idlafkih, Z., and Biger, E.: Variations in trace element geochemistry in the Seine River Basin based on floodplain deposits and bed sediments, Hydrol. Processes, 13, 1329&amp;ndash;40, 1999. </reference>
		<reference numeration="25" content_type="text"> INSEE: 2000 Annual report, Institut National de la Statistique et des Etudes Economiques, Paris, 2002. </reference>
		<reference numeration="26" content_type="text"> IREP: Registre Fran&amp;#x00E7;ais des Emissions Polluantes, 2004, http///www.pollutionsindustrielles.ecologie.gouv.fr/IREP/, Ministère de l&apos;Ecologie et du Développement Durable, Paris, 2004. </reference>
		<reference numeration="27" content_type="text"> Meybeck, M., Lestel, L., Bonté, P., Moilleron, R., Colin, J. L., Rousselot, O., Hervé, D., de Pontevès, C., Grosbois, C., and Thévenot, D. R.: Historical perspective of heavy metals (Cd, Cr, Cu, Hg, Pb, Zn) in the Seine river basin (France) following a DPSIR approach (1950&amp;ndash;2005), Sci. Total Environ., 375, 204&amp;ndash;231, 2007. </reference>
		<reference numeration="28" content_type="text"> Meybeck, M. and Vorosmarty, C.: Fluvial filtering of land-to-ocean fluxes, in : from natural Holocene variations to Anthropocene, C. R. Geosciences, 337, 107&amp;ndash;123, 2005. </reference>
		<reference numeration="29" content_type="text"> Middlekoop, H.: Embanked floodplains in the Netherland, Nederlandsee geographische studies, Utrecht Univ Press, 224 pp., 1997. </reference>
		<reference numeration="30" content_type="text"> Rode, M. and Suhr, U.: Uncertainties in selected river water quality data, Hydrol. Earth Syst. Sci., 11, 863&amp;ndash;874, 2007. </reference>
		<reference numeration="31" content_type="text"> Salomons, W. and Forstner, U.: Metals in the Hydrocycle, Springer Verlag, New York, 1984. </reference>
		<reference numeration="32" content_type="text"> Sörme, L. and Lagerkvist, R.: Sources of heavy metals in urban wastewater in Stockholm, Sci. Total Environ., 298, 131&amp;ndash;145, 2002. </reference>
		<reference numeration="33" content_type="text"> Steffen, W, Sanderson, A., Tyson, P. D., Jager, J., Matson, P. A., Moore, B., Oldfield, F., Richardson, K., Schellnhuber, H. J., Turner, B. L., and Wasson, R. J. (Eds.): Global change and The Earth System, Springer-Verlag, New York, 2004. </reference>
		<reference numeration="34" content_type="text"> Stigliani, W. M., Jaffé, P. R., and Anderberg, S.: Heavy Metal Pollution in the Rhine Basin, Environ. Sci. Technol., 27, 786&amp;ndash;793, 1993. </reference>
		<reference numeration="35" content_type="text"> Thévenot, D. R., Moilleron, R, Lestel, L., Gromaire, M. C., Rocher, V., Cambier, P., Bonté, P., Colin, J. L., de Pontevès, C., and Meybeck, M.: Critical budget of metal sources and pathways in the Seine river basin (1994&amp;ndash;2003) for Cd, Cr, Cu, Hg, Ni, Pb and Zn, Sci. Total Environ., 375, 180&amp;ndash;203, 2007. </reference>
		<reference numeration="36" content_type="text"> Trefry, J. H., Nelsen, T. A., Trocine, R. P., Metz, S., and Vetter, T. W.: Trace metal fluxes through the Mississippi River delta system, in: CIESM Report 186, Contaminant fluxes through the coastal zone, edited by: Kullenberg, G., Monaco, 277&amp;ndash;288, 1986. </reference>
		<reference numeration="37" content_type="text"> Unifa: Les livraisons de fertilisants en France, campagne 2003&amp;ndash;2004, Les chiffres-clés 2005, www.unifa.fr, Union des industries de la fertilisation, Paris, 2005. </reference>
		<reference numeration="38" content_type="text"> Winkels, H. J., Kroonenberg, S. B., Lychagin, M. Y., Marin, G., Rusakov, G. V., and Kasimov, N. S.: Geochronology of priority pollutants in sedimentation zones of the Volga and Danube delta in comparison with the Rhine delta, Appl. Geochem., 13, 581&amp;ndash;591, 1998. </reference>
		<reference numeration="39" content_type="text"> Zwolsman, J. J. G. and van Eck, G. T. M.: Geochemistry of major elements and trace metals in suspended matter of the Scheldt estuary, southwest Netherlands, Marine Chem., 66, 91&amp;ndash;111, 1999. </reference>
	</references>
</article>

