<?xml version="1.0" encoding="utf-8" standalone="no"?>
<!DOCTYPE article SYSTEM "http://www.hydrol-earth-syst-sci.net/inc/hess/copernicus.dtd">
<article language="en">
	<journal>
		<journal_title>Hydrology and Earth System Sciences</journal_title>
		<journal_url>www.hydrol-earth-syst-sci.net</journal_url>
		<issn>1027-5606</issn>
		<eissn>1607-7938</eissn>
		<volume_number>12</volume_number>
		<issue_number>1</issue_number>
		<publication_year>2008</publication_year>
	</journal>
	<doi>10.5194/hess-12-1-2008</doi>
	<article_url>http://www.hydrol-earth-syst-sci.net/12/1/2008/</article_url>
	<abstract_html>http://www.hydrol-earth-syst-sci.net/12/1/2008/hess-12-1-2008.html</abstract_html>
	<fulltext_pdf>http://www.hydrol-earth-syst-sci.net/12/1/2008/hess-12-1-2008.pdf</fulltext_pdf>
	<start_page>1</start_page>
	<end_page>19</end_page>
	<publication_date>2008-01-18</publication_date>
	<article_title content_type="html">A conceptual model of flow to the Waikoropupu Springs, NW Nelson, New Zealand, based on hydrometric and tracer (&lt;sup&gt;18&lt;/sup&gt;O, Cl,&lt;sup&gt;3&lt;/sup&gt;H and CFC) evidence</article_title>
	<authors>
		<author numeration="1" affiliations="1,3">
			<name>M. K. Stewart</name>
			<email>mk.stewart@gns.cri.nz</email>
		</author>
		<author numeration="2" affiliations="2">
			<name>J. T. Thomas</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">GNS Science, Lower Hutt, New Zealand</affiliation>
		<affiliation numeration="2" content_type="html">Tasman District Council, Richmond, New Zealand</affiliation>
		<affiliation numeration="3" content_type="html">now at: Aquifer Dynamics Ltd, Lower Hutt, New Zealand</affiliation>
	</affiliations>
	<abstract content_type="html">The Waikoropupu Springs, a large karst resurgence 4 km from the coast, are
supplied by the Arthur Marble Aquifer (AMA) underlying the Takaka Valley,
South Island, New Zealand. New evidence on the recharge sources in the
catchment, combined with previous results, is used to establish a new
recharge model for the AMA. Combined with the oxygen-18 mass balance, this
yields a quantitative description of the inputs and outputs to the aquifer.
It shows that the Main Spring is sourced mainly from the karst uplands
(74%), with smaller contributions from the Upper Takaka River (18%)
and valley rainfall (8%), while Fish Creek Spring contains mostly Upper
Takaka River water (50%). In addition, much of the Upper Takaka River
contribution to the aquifer (58%) bypasses the springs and is discharged
offshore via submarine springs. The chemical concentrations of the Main
Spring show input of 0.5% of sea water on average, which varies with flow
and derives from the deep aquifer. Tritium measurements spanning 40 yr,
and CFC-11 measurements, give a mean residence time of 8 yr for the Main
Spring water using the preferred two-component model. Our conceptual flow
model, based on the flow, chloride, oxygen-18 and age measurements, invokes
two different flow systems with different recharge sources to explain the
flow within the AMA. One system contains deeply penetrating old water with
mean age 10.2 yr and water volume 3 km&lt;sup&gt;3&lt;/sup&gt;, recharged from the karst
uplands. The other, at shallow levels below the valley floor, has much
younger water with mean age 1.2 yr and water volume 0.4 km&lt;sup&gt;3&lt;/sup&gt;,
recharged by Upper Takaka River and valley rainfall. The flow systems
contribute in different proportions to the Main Spring, Fish Creek Springs
and offshore springs. Their very different behaviours, despite being in the
same aquifer, are attributed to the presence of a diorite intrusion below
the surface of the lower valley, which diverts the deep flow towards the
Waikoropupu Springs and allows much of the shallow flow to pass over the
intrusive and escape via submarine springs.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Bergmann, H., Sackl, B., Maloszewski P., and Stichler, W.: Hydrological investigation in a small catchment area using isotope data series, in: Proceedings of the Fifth International Symposium on Underground Water Tracing. Institute of Geology and Mineral Exploration, Athens, 255&amp;ndash;272, 1986. </reference>
		<reference numeration="2" content_type="text"> Busenberg, E. and Plummer, L. N.: Use of chlorofluorocarbons (CCl&lt;sub&gt;3&lt;/sub&gt;F and CCl&lt;sub&gt;2&lt;/sub&gt;F$_2)$ as hydrologic tracers and age-dating tools: The alluvium and terrace system of Central Oklahoma, Water Resour. Res., 28(5), 2257&amp;ndash;2283, 1992. </reference>
		<reference numeration="3" content_type="text"> Davies-Colley, R. J. and Smith, D. G.: Optically pure waters in Waikoropupu (&quot;Pupu&quot;) Springs, Nelson, New Zealand, New Zeal. J. Mar. Fresh., 29, 251&amp;ndash;256, 1995. </reference>
		<reference numeration="4" content_type="text"> Doyle, M. and Edgar, J.E.: There are no springs in the water balance, New Zealand Hydrological Society 1998 Symposium Proceedings, p. 27, Dunedin, 24&amp;ndash;27 November 1998. </reference>
		<reference numeration="5" content_type="text"> Edgar, J. E.: Hydrogeology of the Takaka Valley, M.Sc. Thesis, University of Canterbury, p 303, 1998. </reference>
		<reference numeration="6" content_type="text"> Elliot, T., Andrews, J. N., and Edmunds, W. M.: Hydrochemical trends, paleorecharge and groundwater ages in the fissured Chalk aquifer of the London and Berkshire Basins, UK Appl. Geochem., 14, 333&amp;ndash;363, 1999. </reference>
		<reference numeration="7" content_type="text"> Fleury, P., Bakalowicz, M., and de Marsily, G.: Submarine springs and coastal karst aquifers: A review, J. Hydrol., 339(1&amp;ndash;2), 79&amp;ndash;92, doi:10.1016/j.jhydrol.2007.03.009, 2007. </reference>
		<reference numeration="8" content_type="text"> Ford, D. C. and Williams, P. W.: Karst Geomorphology and Hydrology, Chapman and Hall, London, 1989. </reference>
		<reference numeration="9" content_type="text"> Jones, W. M.: Magnetic observations in the Onekaka-Parapara District, with some remarks on the geology of the iron-ore deposits, New Zeal. J. Sci., 21B(1), 16&amp;ndash;30, 1939. </reference>
		<reference numeration="10" content_type="text"> Hulston, J. R., Taylor, C. B., Lyon, G. L., Stewart, M. K., and Cox, M. A.: Environmental isotopes in New Zealand hydrology, Part 2: Standards, measurement techniques and reporting of measurements for oxygen-18, deuterium and tritium in water, New Zeal. J. Sci., 24, 313&amp;ndash;322, 1981. </reference>
		<reference numeration="11" content_type="text"> IAEA: Fifth IAEA intercomparison of low-level tritium measurements in water, Report prepared by Östlund, G., Scott, E. M., and Taylor, C. B. for the Isotope Hydrology Section of the I.A.E.A., Vienna, Austria. 1995. </reference>
		<reference numeration="12" content_type="text"> Maloszewski, P. and Zuber, A.: Determining the turnover time of groundwater systems with the aid of environmental tracers, 1. Models and their applicability, J. Hydrol., 57, 207&amp;ndash;331, 1982. </reference>
		<reference numeration="13" content_type="text"> Maloszewski, P., Stichler, W., Zuber, A., and Rank, D.: Identifying the flow systems in a karstic-fissured-porous aquifer, the Schneealpe, Austria, by modelling of environmental $^18$O and &lt;sup&gt;3&lt;/sup&gt;H isotopes, J. Hydrol., 256, 48&amp;ndash;59, 2002. </reference>
		<reference numeration="14" content_type="text"> Michaelis, F. B.: Physico-chemical features of Pupu Springs. New Zeal. J. Mar. Fresh., 10(1), 613&amp;ndash;628, 1976. </reference>
		<reference numeration="15" content_type="text"> Morgenstern, U. and Taylor, C. B.: Low-level tritium measurement using electrolytic enrichment and liquid scintillation counting, Proc. International Symposium on Quality Assurance for Analytical Methods in Isotope Hydrology, Vienna, Austria, 2005. </reference>
		<reference numeration="16" content_type="text"> Mueller, M.: Karst hydrogeology of the Takaka Valley, Golden Bay, northwest Nelson, New Zeal. J. Geol. Geop. 34, 11&amp;ndash;16, 1991. </reference>
		<reference numeration="17" content_type="text"> Mueller, M.: Geohydrology of the Takaka Valley, Unpublished report, Tasman District Council, Richmond, N.Z., 1992. </reference>
		<reference numeration="18" content_type="text"> Park, J.: On the geology of Collingwood County, Nelson, New Zealand Geological Survey report of geological exploration 20, 186&amp;ndash;243, 1890. </reference>
		<reference numeration="19" content_type="text"> Plummer, L. N. and Busenburg, E.: Chlorofluorocarbons, Chapter 15 in Environmental Tracers in Subsurface Hydrology, edited by: Cook, P. and Herczeg, A. L., Kluwer Academic Publishers, 441&amp;ndash;478, 1999. </reference>
		<reference numeration="20" content_type="text"> Rapier, D.: Waikoropupu Springs &amp;ndash; some hydrological aspects, Unpublished report, N.Z. Ministry of Works, Nelson, N.Z., 1975. </reference>
		<reference numeration="21" content_type="text"> Rattenbury, M. A., Cooper, R. A., and Johnston, M. R. (Compilers): Geology of the Nelson Area. IGNS 1:250 000 Geological Map 9, 1 sheet and 1&amp;ndash;67, 1998. </reference>
		<reference numeration="22" content_type="text"> Rank, D., Völkl, G., Maloszewski, P., and Stichler, W.: Flow dynamics in an alpine karst massif studied by means of environmental isotopes. Isotope Techniques in Water Resources Development 1991, IAEA Symposium 319, March 1991, Vienna, 327&amp;ndash;343, 1992. </reference>
		<reference numeration="23" content_type="text"> Rosen, M. R., Cameron, S. G., Taylor, C. B., and Reeves, R. R.: New Zealand guidelines for the collection of groundwater samples for chemical and isotopic analyses, I.G.N.S. Science Report 99/9, 1&amp;ndash;81, 1999. </reference>
		<reference numeration="24" content_type="text"> Siegenthaler, U., Schotterer, U., and Muller, I.: Isotopic and chemical investigations of springs from different karst zones in the Swiss Jura, In Isotope Hydrology 1983, 153&amp;ndash;172, Vienna, IAEA, 1984. </reference>
		<reference numeration="25" content_type="text"> Stewart, M. K. and Downes, C. J.: Isotope hydrology of Waikoropupu Springs, New Zealand, Isotope Studies of Hydrologic Procesess, NIU Press, DeKalb, IL., 15&amp;ndash;23, 1981. </reference>
		<reference numeration="26" content_type="text"> Stewart, M. K. and Morgenstern, U.: Age and source of groundwater from isotope tracers, in: Groundwaters of New Zealand, edited by: Rosen, M. R. and White, P. A., New Zealand Hydrological Society Inc., Wellington., 161&amp;ndash;183, 2001. </reference>
		<reference numeration="27" content_type="text"> Stewart, M. K. and Taylor, C. B.: Environmental isotopes in New Zealand hydrology, 1. Introduction: The role of oxygen-18, deuterium and tritium in hydrology, New Zeal. J. Sci., 24, 295&amp;ndash;311, 1981. </reference>
		<reference numeration="28" content_type="text"> Stewart, M. K. and Williams, P. W.: Environmental isotopes in New Zealand hydrology, 3. Isotope hydrology of Waikoropupu Springs and Takaka River, northwest Nelson, New Zeal. J. Sci., 24, 323&amp;ndash;337, 1981. </reference>
		<reference numeration="29" content_type="text"> Stewart, M. K., Cox, M. A., James, M. R., and Lyon, G. L.: Deuterium in New Zealand rivers and streams, I.N.S. Science Report (INS-R&amp;ndash;20), 1&amp;ndash;32, 1983. </reference>
		<reference numeration="30" content_type="text"> Stewart, M. K., Mehlhorn, J., and Elliott, S.: Hydrometric and natural tracer ($^18$O, silica, &lt;sup&gt;3&lt;/sup&gt;H and SF$_6$) evidence for a dominant groundwater contribution to Pukemanga Stream, New Zealand, Hydrol. Process., 21, 3340&amp;ndash;3356, doi: 10.1002/hyp.6557, 2007. </reference>
		<reference numeration="31" content_type="text"> Taylor, C. B.: The relationship between electrolytic deuterium and tritium separation factors , and attainment of improved accuracy in radiometric low-level tritium measurement, J. Appl. Rad. Isotopes, 45(2), 683&amp;ndash;692, 1994. </reference>
		<reference numeration="32" content_type="text"> Taylor, C. B.: Contributing sources to Waikoropupu Springs, Takaka, NW Nelson: a new assessment, New Zealand Hydrological Society 2001 Symposium Proceedings, 38&amp;ndash;39, Palmerston North, 20&amp;ndash;23 November 2001. </reference>
		<reference numeration="33" content_type="text"> Thomas, Joseph: Groundwater resources of the Tasman Region. In Groundwaters of New Zealand, edited by: Rosen, M. R. and White, P. A., New Zealand Hydrological Society Inc., Wellington., 411&amp;ndash;425, 2001. </reference>
		<reference numeration="34" content_type="text"> Williams, P. W.: Hydrology of the Waikoropupu Springs: a major tidal karst resurgence in northwest Nelson (New Zealand), J. Hydrol., 35, 73&amp;ndash;92, 1977. </reference>
		<reference numeration="35" content_type="text"> Williams, P. W.: Karst systems, Chapter 31 in: Freshwaters of New Zealand, edited by: Harding, J. S., Mosley, M. P., Pearson, C. P., and Sorrell, B. K., New Zeal. Hyd. Soc. and New Zeal. Lim. Soc., Christchurch, New Zealand, 2004. </reference>
		<reference numeration="36" content_type="text"> Williams, P. W.: Limestone Country, Te Ara &amp;ndash; the Encyclopedia of New Zealand, available at: http://www.teara.govt.nz/TheBush/Landscapes/LimestoneCountry/en, 2007. </reference>
	</references>
</article>

