Articles | Volume 22, issue 12
https://doi.org/10.5194/hess-22-6371-2018
https://doi.org/10.5194/hess-22-6371-2018
Research article
 | 
10 Dec 2018
Research article |  | 10 Dec 2018

Caffeine vs. carbamazepine as indicators of wastewater pollution in a karst aquifer

Noam Zach Dvory, Yakov Livshitz, Michael Kuznetsov, Eilon Adar, Guy Gasser, Irena Pankratov, Ovadia Lev, and Alexander Yakirevich

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Subject: Vadose Zone Hydrology | Techniques and Approaches: Modelling approaches
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Cited articles

Ahmed, W., Goonetilleke, A., and Gardner, T.: Detection and quantification of faecal pollution in environmental waters using alternative Faecal indicators: A Brief Review, Water, 39, 46–49, 2008. 
Arye, G., Dror, I., and Berkowitz, B.: Fate and transport of carbamazepine in soil aquifer treatment (SAT) infiltration basin soils, Chemosphere, 82, 244–252, https://doi.org/10.1016/j.chemosphere.2010.09.062, 2011. 
Bertelkamp, C., Reungoat, J., Cornelissen, E. R., Singhal, N., Reynisson, J., Cabo, A. J., van der Hoek, J. P., and Verliefde, A. R. D.: Sorption and biodegradation of organic micropollutants during river bank filtration: a laboratory column study, Water Res., 52, 231–241, 2014. 
Bradley, P. M., Barber, L. B., Kolpin, D. W., McMahon, P. B., and Chapelle, F. H.: Biotransformation of Caffeine, Cotinine, and Nicotine in sream sediments: Implications for use as wastewater indicators, Environ. Toxicol. Chem., 26, 1116, https://doi.org/10.1897/06-483R.1, 2007. 
Bueno, M. J. M., Hernando, M. D., Herrera, S., Gómez, M. J., Fernández-Alba, A. R., Bustamante, I., and García-Calvo, E.: Pilot survey of chemical contaminants from industrial and human activities in river waters of spain, Int. J. Environ. An. Chem., 90, 321–343, https://doi.org/10.1080/03067310903045463, 2010. 
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Short summary
This research is paramount given the significance of karst aquifers as essential drinking water sources. While CBZ is considered conservative, CAF is subject to sorption and degradation, and therefore each of these two pollutants can be considered effective tracers for specific assessment of aquifer contamination. The model presented in this paper shows how each of the mentioned contaminants could serve as a better tool for aquifer contamination characterization and its treatment.