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Hydrology and Earth System Sciences An interactive open-access journal of the European Geosciences Union
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Volume 9, issue 6 | Copyright

Special issue: Water and chemical fluxes through catchments

Hydrol. Earth Syst. Sci., 9, 621-644, 2005
https://doi.org/10.5194/hess-9-621-2005
© Author(s) 2005. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.

  31 Dec 2005

31 Dec 2005

Hydrochemical heterogeneity in an upland catchment: further characterisation of the spatial, temporal and depth variations in soils, streams and groundwaters of the Plynlimon forested catchment, Wales

P. Shand1, A. H. Haria2, C. Neal2, K. J. Griffiths1, D. C. Gooddy1, A. J. Dixon2, T. Hill2, D. K. Buckley1, and J. E. Cunningham1 P. Shand et al.
  • 1British Geological Survey, Maclean Building, Crowmarsh Gifford, Wallingford, Oxfordshire, OX10 8BB, UK
  • 2Centre of Ecology and Hydrology, Maclean Building, Crowmarsh, Gifford, Wallingford, Oxfordshire, OX10 8BB, UK

Abstract. The heterogeneous nature of upland hard-rock catchments in terms of geology, geomorphology, superficial deposits, soil type and land use gives rise to a range of hydrochemical characteristics in stream waters. This is further complicated by the large and often rapid changes in stream flow typical of storm events. The sources of solutes and flow pathways in hard-rock catchments are still poorly understood, in particular the role of bedrock groundwater. Spatial variations in water chemistry are presented for stream waters, soils and groundwaters in the forested Plynlimon catchment of Wales, UK. The results highlight a large degree of spatial heterogeneity in each of these systems. This has major implications for the application of end-member mixing analysis and presents serious problems for modelling in scaling up from study sites to catchment scale. However, such data provide important constraints on sources, flow pathways and residence times within individual catchment compartments, knowledge of which is essential for understanding how such catchments function. The characterisation of sub-surface waters in upland catchments requires a great deal of care during sampling as well as high spatial and temporal resolution of sampling, and further work is required to characterise the Plynlimon catchments fully. Nevertheless, the presence of an active and highly stratified groundwater system is considered important as a source of solutes and water to streams. It also provides a storage medium that is likely to make a major contribution to explaining the strongly damped rainfall Cl and d2H signals measured in the streams.

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